[(1-Azulenyl)methanethiolato-κS](1,4,8,12-tetraazacyclopentadecane-κ4 N)zinc(II) perchlorate
نویسندگان
چکیده
In the title compound, [Zn(C(11)H(26)N(4))(C(11)H(9)S)]ClO(4), the Zn(II) atom is five-coordinated by four N atoms from a neutral 1,4,8,12-tetra-azacyclo-penta-decane aza-macrocycle mol-ecule, and one S atom from an azulenylmethane-thiol-ate ligand. Only monomers are found in the crystal. The coordination geometry can be described as trigonal bipyramidal, with the thiol-ate group in an equatorial position. The Zn-N and Zn-S distances are in the usual ranges for this type of complex.
منابع مشابه
(5,7,7,12,14,14-Hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene-κ4 N 1,N 4,N 8,N 11)(thiocyanato-κS)nickel(II) perchlorate monohydrate
In the title compound, [Ni(SCN)(C(16)H(32)N(4))]ClO(4)·H(2)O, the Ni(II) ion is coordinated by the four N atoms of the tetra-azacyclo-tetra-deca-4,11-diene macrocyclic ligand and by the S atom of a thio-cyanate anion. The perchlorate anion is rotationally disordered around one Cl-O bond between two orientations; the occupancies refined to 0.61 (4) and 0.39 (4). Inter-molecular O-H⋯N, N-H⋯O and ...
متن کامل{N,N′-Bis[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ4 N,N′,N′′,N′′′}(thiocyanato-κN)zinc(II) perchlorate
In the title compound, [Zn(NCS)(C(16)H(18)N(4))]ClO(4), the Zn(II) atom is five-coordinated by four N atoms of the Schiff base ligand N,N'-bis-[1-(2-pyrid-yl)ethyl-idene]ethane-1,2-diamine in the basal plane, and by the N atom of a thio-cyanate ligand at the apical position, forming a distorted square-pyramidal geometry. The r.m.s. deviation from a plane through the four N atoms of the Schiff b...
متن کامل[μ-N,N′-Bis(2-aminoethyl)ethane-1,2-diamine-κ4 N 1,N 1′:N 2,N 2′]bis{[N,N′-bis(2-aminoethyl)ethane-1,2-diamine-κ4 N,N′,N′′,N′′′]cadmium} tetrakis(perchlorate)
The centrosymmetric dinuclear cadmium title complex, [Cd(2)(C(6)H(18)N(4))(3)](ClO(4))(4), was obtained by the reaction of N,N'-bis-(2-amino-eth-yl)ethane-1,2-diamine (trien) with Cd(NO(3))(2)·4H(2)O and sodium perchlorate in methanol. The Cd(II) cation is coordinated by four N atoms of a non-bridging trien ligand and by two N atoms of a bridging trien ligand in a slightly distorted octa-hedral...
متن کامل(Acetato-κO)(2,5,5,7,9,12,12,14-octamethyl-1,4,8,11-tetraazacyclotetradecane-κ4 N,N′,N′′,N′′′)zinc perchlorate
The Zn(II) atom in the cation of the title salt, [Zn(C(2)H(3)O(2))(C(18)H(40)N(4))]ClO(4), is five-coordinated by the four N atoms of the macrocycle and the O atom of the monodentate acetate ligand. The N(4)O donor set is based on a trigonal bipyramid with two N atoms occupying axial positions [N-Zn-N = 170.89 (16)°]. The perchlorate anions are associated with the cations via N-H⋯O hydrogen bon...
متن کاملDiaqua[μ-11,23-di-tert-butyl-3,7,15,19-tetraazatricyclo[19.3.1.19,13]tetracosa-1(25),2,6,9,11,13(26),14,19,21,23-dodecaene-25,26-diolato-κ4 N 3,N 7,O 25,O 26:κ4 N 15,N 19,O 25,O 26]dicopper(II) bis(perchlorate)
In the dinuclear title complex, [Cu(2)(C(30)H(38)N(4)O(2))(H(2)O)(2)](ClO(4))(2), the coordination cation has crystallographically imposed twofold rotational symmetry. The Cu(II) ion is five-coordinated by two N and two O atoms from the macrocylic ligand and one O atom from a water mol-ecule, forming a square-pyramidal N(2)O(3) geometry with the water mol-ecule in the apical position. The dista...
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عنوان ژورنال:
دوره 64 شماره
صفحات -
تاریخ انتشار 2007